Dan Rigel is the current principal. He's young, fresh, new to the job. He has a laidback personality and unconventional approach--if you can get him to focus long enough.
 

Tim O'Ryan is his elder subordinate (and he's bitter about it, too). He's seasoned and professional, and not-so-secretly resentful that the new kid got the promotion. He's bi and has been married to his husband, Harvey, for decades.

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Mr. Montuno is a veteran who fell in love with music via therapy, and comes off intimidating, but is really a softie who's passionate about feeding the soul with the arts. He might have a prosthetic leg.

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Coach Harris is basically your stereotypical coach. A former Eridanus otter herself, she's a die-hard team supporter. She kind of relishes her authority but also resents feeling like she's pulling double duty by also being the health teacher.

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Su Chaophraya is a new, young teacher who's still a bit green and takes herself a little too seriously, which shows in her stricter teaching style.
 

If anyone can make chemistry fun, it's Lydia Zaurak! She's always been eccentric and excitable, but it doesn't come off as well in older age. She can really get into anything she sets her mind to, but loves analytical things. She's also a sci-fi fan and might be a fanfic writer herself. She's likely neurodivergent.